Aromatic flavors of haze on Saturn's largest moon, Titan, recreated

In lab experiments NASA scientists matched the spectral signature of an unknown material the Cassini spacecraft detected in Titan's atmosphere at far-infrared wavelengths. The material contains aromatic hydrocarbons that include nitrogen, a subgroup called polycyclic aromatic nitrogen heterocycles. Credit: NASA/Goddard/JPL

NASA scientists have created a new recipe that captures key flavors of the brownish-orange atmosphere around Saturn's largest moon, Titan.

The recipe is used for lab experiments designed to simulate Titan's chemistry. With this approach, the team was able to classify a previously unidentified material discovered by NASA's Cassini spacecraft in the moon's smoggy haze.

"Now we can say that this material has a strong aromatic character, which helps us understand more about the complex mixture of molecules that makes up Titan's haze," said Melissa Trainer, a planetary scientist at NASA's Goddard Space Flight Center in Greenbelt, Maryland.

The material had been detected earlier in data gathered by Cassini's Composite Infrared Spectrometer, an instrument that makes observations at wavelengths in the far infrared region, beyond red light. The spectral signature of the material suggested it was made up of a mixture of molecules.

To investigate that mixture, the researchers turned to the tried-and-true approach of combining gases in a chamber and letting them react. The idea is that if the experiment starts with the right gases and under the right conditions, the reactions in the lab should yield the same products found in Titan's smoggy atmosphere. The process is like being given a slice of cake and trying to figure out the recipe by tasting it. If you can make a cake that tastes like the original slice, then you chose the right ingredients.

The challenge is that the possibilities are almost limitless in this case. Titan's dirty orange color comes from a mixture of hydrocarbons (molecules that contain hydrogen and carbon) and nitrogen-carrying chemicals called nitriles. The family of hydrocarbons already has hundreds of thousands of members, identified from plants and fossil fuels on Earth, and more could exist.

The logical starting point was to begin with the two gases most plentiful in Titan's atmosphere: nitrogen and methane. But these experiments never produced a mixture with a spectral signature to match to the one seen by Cassini; neither have similar experiments conducted by other groups.

Promising results finally came when the researchers added a third gas, essentially tweaking the flavors in the recipe for the first time. The team began with benzene, which has been identified in Titan's atmosphere, followed by a series of closely related chemicals that are likely to be present there. All of these gases belong to the subfamily of hydrocarbons known as aromatics.

The outcome was best results were obtained when the scientists chose an aromatic that contained nitrogen. When team members analyzed those lab products, they detected spectral features that matched up well with the distinctive signature that had been extracted from the Titan data by Carrie Anderson, a Cassini participating scientist at Goddard and a co-author on this study.

"This is the closest anyone has come, to our knowledge, to recreating with lab experiments this particular feature seen in the Cassini data," said Joshua Sebree, the lead author of the study, available online in Icarus. Sebree is a former postdoctoral fellow at Goddard who is now an assistant professor at the University of Northern Iowa in Cedar Falls.

Now that the basic recipe has been demonstrated, future work will concentrate on tweaking the experimental conditions to perfect it.

"Titan's chemical makeup is veritable zoo of complex molecules," said Scott Edgington, Cassini Deputy Project Scientist at NASA's Jet Propulsion Laboratory in Pasadena, California. "With the combination of laboratory experiments and Cassini data, we gain an understanding of just how complex and wondrous this Earth-like moon really is."

Source: NASA/Goddard Space Flight Center

Swarms of Pluto-size objects kick up dust around adolescent Sun-like star

Artist impression of the debris disk around HD 107146. This adolescent star system shows signs that in its outer reaches, swarms of Pluto-size objects are jostling nearby smaller objects, causing them to collide and "kick up" considerable dust. Credit: A. Angelich (NRAO/AUI/NSF)

Astronomers using the Atacama Large Millimeter/submillimeter Array (ALMA) may have detected the dusty hallmarks of an entire family of Pluto-size objects swarming around an adolescent version of our own Sun.

By making detailed observations of the protoplanetary disk surrounding the star known as HD 107146, the astronomers detected an unexpected increase in the concentration of millimeter-size dust grains in the disk's outer reaches. This surprising increase, which begins remarkably far -- about 13 billion kilometers -- from the host star, may be the result of Pluto-size planetesimals stirring up the region, causing smaller objects to collide and blast themselves apart.

Dust in debris disks typically consists of material left over from the formation of planets. 

Very early in the lifespan of the disk, this dust is continuously replenished by collisions of larger bodies, such as comets and asteroids. In mature solar systems with fully formed planets, comparatively little dust remains. In between these two ages -- when a solar system is in its awkward teenage years -- certain models predict that the concentration of dust would be much denser in the most distant regions of the disk. This is precisely what ALMA has found.

"The dust in HD 107146 reveals this very interesting feature -- it gets thicker in the very distant outer reaches of the star's disk," said Luca Ricci, an astronomer at the Harvard-Smithsonian Center for Astrophysics (CfA), and lead author on a paper accepted for publication in the Astrophysical Journal. At the time of the observations, Ricci was with the California Institute of Technology.

"The surprising aspect is that this is the opposite of what we see in younger primordial disks where the dust is denser near the star. It is possible that we caught this particular debris disk at a stage in which Pluto-size planetesimals are forming right now in the outer disk while other Pluto-size bodies have already formed closer to the star," said Ricci.

According to current computer models, the observation that the density of dust is higher in the outer regions of the disk can only be explained by the presence of recently formed Pluto-sized bodies. Their gravity would disturb smaller planetesimals, causing more frequent collisions that generate the dust ALMA sees.

The new ALMA data also hint at another intriguing feature in the outer reaches of the disk: a possible "dip" or depression in the dust about 1.2 billion kilometers wide, beginning approximately 2.5 times the distance of the Sun to Neptune from the central star. Though only suggested in these preliminary observations, this depression could be a gap in the disk, which would be indicative of an Earth-mass planet sweeping the area clear of debris. Such a feature would have important implications for the possible planet-like inhabitants of this disk and may suggest that Earth-size planets could form in an entirely new range of orbits than have ever been seen before.

The star HD 107146 is of particular interest to astronomers because it is in many ways a younger version of our own Sun. It also represents a period of transition from a solar system's early life to its more mature, final stages where planets have finished forming and have settled into their final orbits around their host star.

"This system offers us the chance to study an intriguing time around a young, Sun-like star," said ALMA Deputy Director and coauthor Stuartt Corder. "We are possibly looking back in time here, back to when the Sun was about 2 percent of its current age."

The star HD 107146 is located approximately 90 light-years from Earth in the direction of the constellation Coma Berenices. It is approximately 100 million years old. Further observations with ALMA's new long-baseline, high-resolution capabilities will shed more light on the dynamics and composition of this intriguing object.

Source: Harvard-Smithsonian Center for Astrophysics