Stanford scientists use ocean waves to monitor offshore oil and gas fields

A new technique for passively probing the sea floor using weak seismic waves generated by the ocean was tested at the Ekofisk oil field in the North Sea. 

A technology developed by Stanford scientists for passively probing the seafloor using weak seismic waves generated by the ocean could revolutionize offshore oil and natural gas extraction by providing real-time monitoring of the subsurface while lessening the impact on marine life.

"We've shown that we can generate images of the subsurface nearly every day instead of taking snapshots just two or three times a year," said Biondo Biondi, professor of geophysics at Stanford's School of Earth Sciences.

Currently, many energy companies use a technique called time-lapse reflection seismology to monitor offshore oil and gas deposits to optimize production and look for hazards such as hidden gas pockets. Reflection seismology involves ships towing arrays of "air guns" that explode every 10 to 15 seconds to produce loud sound pulses. The pulses bounce off the seafloor and geological formations beneath, then journey back to the surface, where they are recorded by hydrophones. The data are then deciphered to reveal details about subsurface structures.

Each survey can cost tens of millions of dollars, and as a result they are only conducted two to three times a year. Environmental groups and marine biologists have expressed concerns about the use of air guns for contributing to noise pollution in the ocean that can disturb or even injure marine animals, including humpback whales and giant squid.

The new technique developed by Biondi and Sjoerd de Ridder, a student of Biondi's who is now a postdoctoral scientist at the University of Edinburgh, is different. It exploits naturally occurring seismic waves generated by Earth's oceans that are several orders of magnitude weaker than those produced by earthquakes.

Ambient seismicity

As ocean waves collide with one another, they create pressures on the sea floor, where they generate seismic waves that then propagate in every direction. Scientists have known about this "ambient seismic field" for nearly a century, but it was only recently that they understood ways to harness it.

"We knew the ambient seismic energy was there, but we didn't know what we could do with it," De Ridder said. "That understanding has only been developed in recent years. Our technique provides the first large-scale application to harness it for oil and gas production."

The technique that Biondi and De Ridder developed, called ambient seismic field noise-correlation tomography, or ASNT, uses sensors embedded in the seafloor. The sensors, which are typically installed by robotic submersibles, are connected to one another by cables and arranged into parallel rows that can span several kilometers of the seafloor. Another cable connects the sensor array to a platform in order to collect data in real time.

The sensors record ambient seismic waves traveling through Earth's crust. The waves are ubiquitous, continuously generated and traveling in every direction, but using careful signal-processing schemes they developed, Biondi and De Ridder can digitally isolate only those waves that are passing through one sensor and then another one downstream. When this is done repeatedly, and for multiple sensors in the network, what emerges is a "virtual" seismic wave pattern that is remarkably similar to the kind generated by air guns.

Less disruptive

Because the ASNT technique is entirely passive, meaning it does not require a controlled explosion or a loud air gun blast to create a seismic wave signature, it can be performed for a fraction of the cost of an active-reflection-seismology survey and should be far less disruptive to marine life, the scientists say.

Since 2007, Biondi and De Ridder have been testing and refining their technique in a real-world laboratory in Europe. The scientists worked with the energy companies BP and ConocoPhillips to study recordings from existing sensor arrays in the Valhall and Ekofisk oil fields in the North Sea that are capable of recording ambient seismic waves.

The proof-of-concept experiment has been successful, and the scientists have demonstrated that they can image the subsurface at Valhall down to a depth of nearly 1,000 feet. "We've now shown that our technique can very reliably and repeatedly retrieve an image of the near-surface," De Ridder said. "Our hope is that they can also reveal changes in the rocks that could signal an impending problem."

Source: Stanford

Put a plastic bag in your tank: Converting polyethylene waste into liquid fuel

Researchers in India have developed a relatively low-temperature process to convert certain kinds of plastic waste into liquid fuel as a way to re-use discarded plastic bags and other products.

Researchers in India have developed a relatively low-temperature process to convert certain kinds of plastic waste into liquid fuel as a way to re-use discarded plastic bags and other products. They report full details next month in the International Journal of Environment and Waste Management.

Many pundits describe the present time as the "plastic age" for good reason and as such we generate a lot plastic waste. Among that waste is the common polymer, low-density polyethylene (LDPE), which is used to make many types of container, medical and laboratory equipment, computer components and, of course, plastic bags. Recycling initiatives are in place in many parts of the world, but much of the polyethylene waste ends up in landfill, dispersed in the environment or in the sea.

Chemist Achyut Kumar Panda of Centurion University of Technology and Management Odisha, India is working with chemical engineer Raghubansh Kumar Singh of the National Institute of Technology, Orissa, India, to develop a commercially viable technology for efficiently rendering LDPE into a liquid fuel. Given that most plastics are made from petrochemicals, this solution to plastic recycling brings the life-cycle full circle allowing a second use as an oil substitute. The process could, if implemented on a large enough scale, reduce pressures on landfill as well as ameliorating the effects of dwindling oil supplies in a world with increasing demands on petrochemicals for fuel.

In their approach, the team heats the plastic waste to between 400 and 500 Celsius over a kaolin catalyst. This causes the plastic's long chain polymer chains to break apart in a process known as thermo-catalytic degradation. This releases large quantities of much smaller, carbon-rich molecules. The team used the analytical technique of gas chromatography coupled mass spectrometry to characterize these product molecules and found the components of their liquid fuel to be mainly paraffins and olefins 10 to 16 carbon atoms long. This, they explain, makes the liquid fuel very similar chemically to conventional petrochemical fuels.

In terms of the catalyst, Kaolin is a clay mineral -- containing aluminum and silicon. It acts as a catalyst by providing a large reactive surface on which the polymer molecules can sit and so be exposed to high temperature inside the batch reactor, which breaks them apart. The team optimized the reaction at 450 Celsius a temperature with the lowest amount of kaolin at which more than 70% of the liquid fuel is produced. In other words, for every kilogram of waste plastic they could produce 700 grams of liquid fuel. The byproducts were combustible gases and wax. They could boost the yield to almost 80% and minimize reaction times, but this required a lot more catalyst 1 kg of kaolin for every 2 kg of plastic.

Source: Inderscience Publishers