New technique could lead to cheaper, more efficient solar power and LEDs

Researchers Valerio Adinolfi (left) and Riccardo Comin examine a perovskite crystal. Perovskites are attracting growing interest in the context of thin-film solar technologies, but had never been studied in their purest form: as perfect single crystals. Credit; Toronto

U of T experts are shining new light on an emerging family of solar-absorbing materials that could lead to cheaper and more efficient solar panels and LEDs.

The materials, called perovskites, are particularly good at absorbing visible light, but had never been studied in their purest form: as perfect single crystals.

Using a new technique, researchers grew large, pure perovskite crystals and studied how electrons move through the material as light is converted to electricity.

Led by Professor Ted Sargent of The Edward S. Rogers Sr. Department of Electrical & Computer Engineering at the University of Toronto in collaboration with Professor Osman Bakr of the King Abdullah University of Science and Technology (KAUST), the team used a combination of laser-based techniques to measure selected properties of the perovskite crystals.

By tracking down the ultrafast motion of electrons in the material, they have been able to measure the diffusion length – how far electrons can travel without getting trapped by imperfections in the material – as well as mobility – how fast the electrons can move through the material. Their work was published this week in the journal Science.

“Our work sets the bar for the ultimate solar energy-harvesting performance of perovskites,” says Riccardo Comin, a post-doctoral fellow with the Sargent Group. “With these materials it’s been a race to try to get record efficiencies, and there are no signs of stopping or slowing down.”

In recent years, perovskite efficiency has soared to over 20 per cent, very close to the current best performance of commercial-grade silicon-based solar panels you see mounted in Spanish deserts and on Californian roofs.

“In terms of efficiency, perovskites are perfectly comparable or better than materials that have already been commercialized,” says Valerio Adinolfi, a PhD candidate in the Sargent Group and co-first author on the paper. “The challenge is to make solar attractive from the business side. It’s not just matter of making it efficient – the point is to make it efficient and cheap.”

The study has obvious implications for green energy, but may also enable innovations in lighting.

Think of a solar panel made of perovskite crystals as a fancy slab of glass: light hits the crystal surface and gets absorbed, exciting electrons in the material. Those electrons travel easily through the crystal to electrical contacts on its underside, where they are collected in the form of electric current.

Now imagine the sequence in reverse – power the slab with electricity, inject electrons and release energy as light. A more efficient electricity-to-light conversion means perovskites could open new frontiers for energy-efficient LEDs.

Parallel work in the Sargent Group focuses on improving nano-engineered solar-absorbing particles called colloidal quantum dots. “Perovskites are great visible-light harvesters, and quantum dots are great for infrared,” said Sargent.

“In future, we will explore the opportunities for stacking together complementary absorbent materials,” says Dr. Comin. “There are very promising prospects for combining perovskite work and quantum dot work for further boosting the efficiency.”

Source: U of T

Defects in solar cells made of silicon identified

Sergio Castellanos wants continue researching, work in an industry and does not rule out to eventually move to another country. Credit: Image courtesy of Investigación y Desarrollo

Since he was a teenager, engineer Sergio Castellanos had the desire to study abroad to prepare and do research in the best laboratories, particularly on solar energy. With six years of stay in the United States, first at the University of Arizona and now at the Massachusetts Institute of Technology (MIT) in Boston, his dream has come true:

"Working on defects found on silicon and their impact on the efficiency of solar cells made with this material."

This research is carried out to obtain his doctorate from MIT.

"Dislocation is a defect that occurs at high temperatures, of 500 ° C onwards. In my research I analyze these defects and their impact on the efficiency of solar cells made from silicon, since this material is used in over 90 percent of solar panels worldwide ."

The Mexican researcher in Boston explains that the harmful part of the dislocation is interacting with other defects such as metallic impurities within the material of solar cells; they tend to reduce efficiency by -for example- interacting with electrons.

"When having a dislocation is very easy for impurities to settle into a defect in the material. Therefore, in my research I analyze at an early scale what kind of dislocations will be more harmful to the cells, meaning, which ones will interact more with impurities because not all do likewise, hence not all dislocations are equally harmful."

The proposal of Sergio Castellanos at the MIT is to apply a method in wafers of polycrystalline silicon before being processed into solar cells. This method involves using a chemical treatment in order to view the dislocations and analyze the geometric variation on the surface. After making crystallographic analysis as well as X-rays for determining the distribution and concentration of metal impurities, a correlation is made with the geometric appearance of the surface and then, just by looking at the surface, one can deduce what the electrical behavior within material will be.

"The goal is to identify which areas of the material will be more likely for electrons to recombine before being extracted by contacts, becoming less efficient cells."

A little bit of history

When the native of Hermosillo, Sonora (northern state of Mexico), was in high school, he applied for the Massachusetts Institute of Technology (MIT) and was not admitted. He told himself he would not be discouraged because surely the opportunity would could come later. He decided to study mechanical engineering at the Technological Institute of Hermosillo and two years in his parents supported him to finish his degree abroad.

He was transferred to the University of Arizona where he finished his degree. At the university, he became involved in several projects on the subject of energy, as was the case with hydrogen cells, a solar car and installing solar panels.

The Mexican says he enjoyed doing research and started looking for projects and teachers who worked in that area. He spotted four scientists, but wanted to go to MIT because "for any engineer to be in this school is a dream. I had practice in energy research during my bachelor's and for my doctorate I looked for subjects in this area. I applied at several universities and at last I was admitted at MIT in Boston."

His research in solar cells is in the last stage, and once completed in the next year he will make it available to other researchers. This work was presented at various conferences and has received good reviews in terms of utility.

To "finish the tale" on solar cells, the Mexican will complete his studies in six to eight months, and is more than satisfied with the subject that has developed during his research.

Sergio Castellanos wants continue researching, work in an industry and does not rule out to eventually move to another country. In the remaining months he will define his next step. (Agencia ID)

Source: Investigación y Desarrollo

Glimpsing pathway of sunlight to electricity

Andrew H. Marcus and Mark C. Lonergan stand by UO spectroscopy equipment. Credit: Image courtesy of University of Oregon

Four pulses of laser light on nanoparticle photocells in a University of Oregon spectroscopy experiment has opened a window on how captured sunlight can be converted into electricity.

The work, which potentially could inspire devices with improved efficiency in solar energy conversion, was performed on photocells that used lead-sulfide quantum dots as photoactive semiconductor material. The research is detailed in a paper placed online by the journal Nature Communications.

In the process studied, each single photon, or particle of sunlight, that is absorbed potentially creates multiple packets of energy called excitons. These packets can subsequently generate multiple free electrons that generate electricity in a process known as multiple exciton generation (MEG). In most solar cells, each absorbed photon creates just one potential free electron.

Multiple exciton generation is of interests because it can lead to solar cells that generate more electrical current and make them more efficient. The UO work shines new light on the little understood process of MEG in nanomaterials.

While the potential importance of MEG in solar energy conversion is under debate by scientists, the UO spectroscopy experiment -- adapted in a collaboration with scientists at Sweden's Lund University -- should be useful for studying many other processes in photovoltaic nanomaterials, said Andrew H. Marcus, professor of physical chemistry and head of the UO Department of Chemistry and Biochemistry.

Spectroscopic experiments previously designed by Marcus to perform two-dimensional fluorescence spectroscopy of biological molecules were adapted to also measure photocurrent. "Spectroscopy is all about light and molecules and what they do together," Marcus said. "It is a really great probe that helps to tell us about the reaction pathway that connects the beginning of a chemical or physical process to its end.

"The approach is similar to looking at how molecules come together in DNA, but instead we looked at interactions within semiconductor materials," said Marcus, an affiliate in UO's Institute of Molecular Biology, Materials Science Institute and Oregon Center for Optics. "Our method made it possible to look at electronic pathways involved in creating multiple excitons. The existence of this phenomenon had only been inferred through indirect evidence. We believe we have seen the initial steps that lead to MEG-mediated photo conductivity."

The controlled sequencing of laser pulses allowed the seven-member research team to see -- in femtoseconds (a femtosecond is one millionth of one billionth of a second) -- the arrival of light, its interaction with resting electrons and the subsequent conversion into multiple excitons. The combined use of photocurrent and fluorescence two-dimensional spectroscopy, Marcus said, provided complementary information about the reaction pathway.

UO co-author Mark C. Lonergan, professor of physical and materials chemistry, who studies electrical and electrochemical phenomena in solid-state systems, likened the processes being observed to people moving through a corn maze that has one entrance and three exits.
People entering the maze are photons. Those who exit quickly represent absorbed photons that generate unusable heat. People leaving the second exit represent other absorbed photons that generate fluorescence but not usable free electrons. People leaving the final exit signify usable electrical current.

"The question we are interested in is exactly what does the maze look like," Lonergan said. "The problem is we don't have good techniques to look inside the maze to discover the possible pathways through it. The techniques that Andy has developed basically allow us to see into the maze by encoding what is coming out of the system in terms of exactly what is going in. We can visualize what is going on, whether two people coming into the maze shook hands at some point and details about the pathway that led them to come out the electricity exit."

The project began when Tonu Pullerits, who studies ultrafast photochemistry in semiconductor molecular materials at Lund University, approached Marcus about adopting his spectroscopic system to look at solar materials. Khadga J. Karki, a postdoctoral researcher in Pullerits' lab, then visited the UO and teamed with the Marcus and Lonergan groups to reconfigure the equipment.

UO doctoral student Julia R. Widom was a co-leading author on the paper. Other co-authors with Pullerits, Marcus and Lonergan were Joachim Seibt of Lund University and UO graduate student Ian Moody.

Source:  University of Oregon

Scientists get to the heart of fool's gold as a solar material

This crystal of iron pyrite shows the characteristic cubic crystals of 'fool's gold.' A new study led by Song Jin at the University of Wisconsin-Madison identifies defects in pyrite's crystal structure as a critical obstacle to building commercial solar cells from the cheap and abundant iron pyrite material. Credit: University of Wisconsin-Madison Geology Museum

As the installation of photovoltaic solar cells continues to accelerate, scientists are looking for inexpensive materials beyond the traditional silicon that can efficiently convert sunlight into electricity.

Theoretically, iron pyrite -- a cheap compound that makes a common mineral known as fool's gold -- could do the job, but when it works at all, the conversion efficiency remains frustratingly low. Now, a University of Wisconsin-Madison research team explains why that is, in a discovery that suggests how improvements in this promising material could lead to inexpensive yet efficient solar cells.

"We think we now understand why pyrite hasn't worked," says chemistry Professor Song Jin, "and that provides the hope, based on our understanding, for figuring out how to make it work. This could be even more difficult, but exciting and rewarding."

Although most commercial photovoltaic cells nowadays are based on silicon, the light-collecting film must be relatively thick and pure, which makes the production process costly and energy-intensive, says Jin.

A film of iron pyrite -- a compound built of iron and sulfur atoms -- could be 1,000 times thinner than silicon and still efficiently absorb sunlight.

Like silicon, iron and sulfur are common elements in Earth's crust, so solar cells made of iron pyrite could have a significant material cost advantage in large scale deployment. In fact, previous research that balanced factors like theoretical efficiency, materials availability, and extraction cost put iron pyrite at the top of the list of candidates for low-cost and large-scale photovoltaic materials.

In the current online edition of the Journal of the American Chemical Society, Jin and first author Miguel Cabán-Acevedo, a chemistry Ph.D. student, together with other scientists at UW-Madison, explain how they identified defects in the body of the iron pyrite material as the source of inefficiency. The research was supported by the U.S. Department of Energy.
In a photovoltaic material, absorption of sunlight creates oppositely charged carriers, called electrons and holes, that must be separated in order for sunlight to be converted to electricity. The efficiency of a photovoltaic solar cell can be judged by three parameters, Jin says, and the solar cells made of pyrite were almost totally deficient in one: voltage. Without a voltage, a cell cannot produce any power, he points out. Yet based on its essential parameters, iron pyrite should be a reasonably good solar material. "We wanted to know, why is the photovoltage so low," Jin says.

"We did a lot of different measurements and studies to look comprehensively at the problem," says Cabán-Acevedo, "and we think we have fully and definitively shown why pyrite, as a solar material, has not been efficient."

In exploring why pyrite was practically unable to make photovoltaic electricity, many researchers have looked at the surface of the crystals, but Cabán-Acevedo and Jin also looked inside. "If you think of this as a body, many have focused on the skin, but we also looked at the heart," says Cabán-Acevedo, "and we think the major problems lie inside, although there are also problems on the skin."

The internal problems, called "bulk defects," occur when a sulfur atom is missing from its expected place in the crystal structure. These defects are intrinsic to the material properties of iron pyrite and are present even in ultra-pure crystals. Their presence in large numbers eventually leads to the lack of photovoltage for solar cells based on iron pyrite crystals.
Science advances by comprehending causes, Jin says. "Our message is that now we understand why pyrite does not work. If you don't understand something, you must try to solve it by trial and error. Once you understand it, you can use rational design to overcome the obstacle. You don't have to stumble around in the dark."

Source: University of Wisconsin-Madison

A New technique could harvest more of the sun's energy

An ultra-sensitive needle measures the voltage that is generated while the nanospheres are illuminated.
Credit: AMOLF/Tremani - Figure: Artist impression of the plasmo-electric effect.

As solar panels become less expensive and capable of generating more power, solar energy is becoming a more commercially viable alternative source of electricity. However, the photovoltaic cells now used to turn sunlight into electricity can only absorb and use a small fraction of that light, and that means a significant amount of solar energy goes untapped.

A new technology created by researchers from Caltech, and described in a paper published online in the October 30 issue of Science Express, represents a first step toward harnessing that lost energy.

Sunlight is composed of many wavelengths of light. In a traditional solar panel, silicon atoms are struck by sunlight and the atoms' outermost electrons absorb energy from some of these wavelengths of sunlight, causing the electrons to get excited. Once the excited electrons absorb enough energy to jump free from the silicon atoms, they can flow independently through the material to produce electricity. This is called the photovoltaic effect -- a phenomenon that takes place in a solar panel's photovoltaic cells.

Although silicon-based photovoltaic cells can absorb light wavelengths that fall in the visible spectrum -- light that is visible to the human eye -- longer wavelengths such as infrared light pass through the silicon. These wavelengths of light pass right through the silicon and never get converted to electricity -- and in the case of infrared, they are normally lost as unwanted heat.

"The silicon absorbs only a certain fraction of the spectrum, and it's transparent to the rest. If I put a photovoltaic module on my roof, the silicon absorbs that portion of the spectrum, and some of that light gets converted into power. But the rest of it ends up just heating up my roof," says Harry A. Atwater, the Howard Hughes Professor of Applied Physics and Materials Science; director, Resnick Sustainability Institute, who led the study.
Now, Atwater and his colleagues have found a way to absorb and make use of these infrared waves with a structure composed not of silicon, but entirely of metal.

The new technique they've developed is based on a phenomenon observed in metallic structures known as plasmon resonance. Plasmons are coordinated waves, or ripples, of electrons that exist on the surfaces of metals at the point where the metal meets the air.
While the plasmon resonances of metals are predetermined in nature, Atwater and his colleagues found that those resonances are capable of being tuned to other wavelengths when the metals are made into tiny nanostructures in the lab.

"Normally in a metal like silver or copper or gold, the density of electrons in that metal is fixed; it's just a property of the material," Atwater says. "But in the lab, I can add electrons to the atoms of metal nanostructures and charge them up. And when I do that, the resonance frequency will change."

"We've demonstrated that these resonantly excited metal surfaces can produce a potential" -- an effect very similar to rubbing a glass rod with a piece of fur: you deposit electrons on the glass rod. "You charge it up, or build up an electrostatic charge that can be discharged as a mild shock," he says. "So similarly, exciting these metal nanostructures near their resonance charges up those metal structures, producing an electrostatic potential that you can measure."

This electrostatic potential is a first step in the creation of electricity, Atwater says. "If we can develop a way to produce a steady-state current, this could potentially be a power source. He envisions a solar cell using the plasmoelectric effect someday being used in tandem with photovoltaic cells to harness both visible and infrared light for the creation of electricity.

Although such solar cells are still on the horizon, the new technique could even now be incorporated into new types of sensors that detect light based on the electrostatic potential.
"Like all such inventions or discoveries, the path of this technology is unpredictable," Atwater says. "But any time you can demonstrate a new effect to create a sensor for light, that finding has almost always yielded some kind of new product."


This work was published in a paper titled, "Plasmoelectric Potentials in Metal Nanostructures." Other coauthors include first author Matthew T. Sheldon, a former postdoctoral scholar at Caltech; Ana M. Brown, an applied physics graduate student at Caltech; and Jorik van de Groep and Albert Polman from the FOM Institute AMOLF in Amsterdam. The study was funded by the Department of Energy, the Netherlands Organization for Scientific Research, and an NSF Graduate Research Fellowship.

Source: California Institute of Technology

In world first, researchers convert sunlight to electricity with over 40 percent efficiency

Solar panels

UNSW Australia's solar researchers have converted over 40% of the sunlight hitting a solar system into electricity, the highest efficiency ever reported.

The record efficiency was achieved in outdoor tests in Sydney, before being independently confirmed by the National Renewable Energy Laboratory (NREL) at their outdoor test facility in the United States.

The work was funded by the Australian Renewable Energy Agency (ARENA) and supported by the Australia-US Institute for Advanced Photovoltaics (AUSIAPV).

"This is the highest efficiency ever reported for sunlight conversion into electricity," UNSW Scientia Professor and Director of the Advanced Centre for Advanced Photovoltaics (ACAP) Professor Martin Green said.

"We used commercial solar cells, but in a new way, so these efficiency improvements are readily accessible to the solar industry," added Dr Mark Keevers, the UNSW solar scientist who managed the project.

The 40% efficiency milestone is the latest in a long line of achievements by UNSW solar researchers spanning four decades. These include the first photovoltaic system to convert sunlight to electricity with over 20% efficiency in 1989, with the new result doubling this performance.

"The new results are based on the use of focused sunlight, and are particularly relevant to photovoltaic power towers being developed in Australia," Professor Green said.

Power towers are being developed by Australian company, RayGen Resources, which provided design and technical support for the high efficiency prototype. Another partner in the research was Spectrolab, a US-based company that provided some of the cells used in the project.

A key part of the prototype's design is the use of a custom optical bandpass filter to capture sunlight that is normally wasted by commercial solar cells on towers and convert it to electricity at a higher efficiency than the solar cells themselves ever could.

Such filters reflect particular wavelengths of light while transmitting others.

ARENA CEO Ivor Frischknecht said the achievement is another world first for Australian research and development and further demonstrates the value of investing in Australia's renewable energy ingenuity.

"We hope to see this home grown innovation take the next steps from prototyping to pilot scale demonstrations. Ultimately, more efficient commercial solar plants will make renewable energy cheaper, increasing its competitiveness."

The 40% efficiency achievement is outlined in a paper expected to be published soon by the Progress in Photovoltaics journal. It will also be presented at the Australian PV Institute's Asia-Pacific Solar Research Conference, which begins at UNSW Monday, December 8.

Source: University of New South Wales.