New technique could lead to cheaper, more efficient solar power and LEDs

Researchers Valerio Adinolfi (left) and Riccardo Comin examine a perovskite crystal. Perovskites are attracting growing interest in the context of thin-film solar technologies, but had never been studied in their purest form: as perfect single crystals. Credit; Toronto

U of T experts are shining new light on an emerging family of solar-absorbing materials that could lead to cheaper and more efficient solar panels and LEDs.

The materials, called perovskites, are particularly good at absorbing visible light, but had never been studied in their purest form: as perfect single crystals.

Using a new technique, researchers grew large, pure perovskite crystals and studied how electrons move through the material as light is converted to electricity.

Led by Professor Ted Sargent of The Edward S. Rogers Sr. Department of Electrical & Computer Engineering at the University of Toronto in collaboration with Professor Osman Bakr of the King Abdullah University of Science and Technology (KAUST), the team used a combination of laser-based techniques to measure selected properties of the perovskite crystals.

By tracking down the ultrafast motion of electrons in the material, they have been able to measure the diffusion length – how far electrons can travel without getting trapped by imperfections in the material – as well as mobility – how fast the electrons can move through the material. Their work was published this week in the journal Science.

“Our work sets the bar for the ultimate solar energy-harvesting performance of perovskites,” says Riccardo Comin, a post-doctoral fellow with the Sargent Group. “With these materials it’s been a race to try to get record efficiencies, and there are no signs of stopping or slowing down.”

In recent years, perovskite efficiency has soared to over 20 per cent, very close to the current best performance of commercial-grade silicon-based solar panels you see mounted in Spanish deserts and on Californian roofs.

“In terms of efficiency, perovskites are perfectly comparable or better than materials that have already been commercialized,” says Valerio Adinolfi, a PhD candidate in the Sargent Group and co-first author on the paper. “The challenge is to make solar attractive from the business side. It’s not just matter of making it efficient – the point is to make it efficient and cheap.”

The study has obvious implications for green energy, but may also enable innovations in lighting.

Think of a solar panel made of perovskite crystals as a fancy slab of glass: light hits the crystal surface and gets absorbed, exciting electrons in the material. Those electrons travel easily through the crystal to electrical contacts on its underside, where they are collected in the form of electric current.

Now imagine the sequence in reverse – power the slab with electricity, inject electrons and release energy as light. A more efficient electricity-to-light conversion means perovskites could open new frontiers for energy-efficient LEDs.

Parallel work in the Sargent Group focuses on improving nano-engineered solar-absorbing particles called colloidal quantum dots. “Perovskites are great visible-light harvesters, and quantum dots are great for infrared,” said Sargent.

“In future, we will explore the opportunities for stacking together complementary absorbent materials,” says Dr. Comin. “There are very promising prospects for combining perovskite work and quantum dot work for further boosting the efficiency.”

Source: U of T

The Ancient exoplanet discovery boosts chances of finding alien life

An artist's impression of the oldest known system of terrestrial-sized planets, Kepler-444. Tiago Campante/Peter Devine, University of Birmingham, Author provided Credit: By Daniel Huber, Astronomer at University of Sydney

One of the crucial variables in calculating the likelihood that alien life exists elsewhere in our galaxy is the number of stars that possess planetary systems, and the proportion of those planets that might be suitable for life.

So the discovery of no less than five sub-Earth-sized exoplanets orbiting an ancient star, Kepler-444, which is not too distant from our own solar system, has significant ramifications for the possibility we might one day run into ET.

Formed over 11-billion years ago, the Kepler-444 system proves that such small planets have existed through most of the history of our universe. And the more small planets that exist, the higher the chances that one of them (or one of their moons) might sit in the so-called “Goldilocks zone” that enables life to exist.

This remarkable discovery was made possible not only by the space-based NASA Kepler telescope but also a technique called asteroseismology.

Kepler continuously measured the brightness of more than 150,000 stars for four years. As planets orbit in front of the stellar disc they cause small dips in the brightness of the star, yielding information on the planet’s orbital period and size relative to the size of their host star.

More than 1,800 exoplanets have been discovered to date, including some Earth-sized planets in the habitable zone. Such discoveries have demonstrated that planets with favourable conditions for life may actually be common.

But the age of the host stars – and therefore the age of the planets – was often unknown. This is because the clues that give a hint to the age of a star tend to be hidden beneath its visible surface.

Using asteroseismology to date a star

An artist’s impression of Kepler-10, illustrating the paths of sound waves in the stellar interior which can be used to determine the fundamental properties – including age – of planet host stars. Gabriel Perez Diaz, Instituto de Astrofisica de Canarias

Fortunately, the variability in the brightness of stars offers a way to resolve this problem using asteroseismology.

Stars with similar and cooler temperatures than our sun transport energy to their surface through the up-flow and down-flow of gas that flows due to the interplay of buoyancy and gravity. The turbulent motion of the gas excites pressure waves to travel through the stellar interior.

The frequency of these waves – also referred to as oscillations – are determined by the sound speed, which in turn depends on the stellar interior structure and composition.

These oscillations also travel to different depths within the star, thereby offering a way to probe the structure by observing the oscillations. As the core properties of the star change with time, such changes are imprinted in the oscillation frequency patterns.

Conveniently, we can measure stellar oscillations using the same data we use to discover transiting planets. Thus we were able to use asteroseismology to study a fascinating planetary system in exquisite detail and to determine the age of the host star.


Kepler-444: An ancient laboratory for planetary and stellar astrophysics

Comparison of the sizes of inner solar system planets to the planets discovered in the Kepler-444 system. Daniel Huber & NASA

Unlike our solar system, however, the Kepler-444 planets orbit their host star in less than 10 days. Even taking into account the cooler temperature of Kepler-444 compared to our sun, this places these ancient planets well outside the habitable zone.

Despite the rather hostile environment, Kepler-444 marks an important milestone to understand whether life may be common outside the solar system. While the Kepler mission has previously demonstrated that small planets are abundant, Kepler-444 proves that such planets have formed for most of the history of our universe.

If life can form on Earth-sized planets in the habitable zone of other stars, this implies that it may have formed on distant planets long before life emerged here on Earth.

Source: University of Sydney

SOHO and Hinode Offer New Insight Into Solar Eruptions

Scientists are trying to understand the precise details of what creates giant explosions in the sun's atmosphere, such as this solar eruption from Oct. 14, 2012, as seen by NASA's Solar Dynamic Observatory. Image Credit: NASA/SDO/Amari

The sun is home to the largest explosions in the solar system. For example, it regularly produces huge eruptions known as coronal mass ejections – when billions of tons of solar material erupt off the sun, spewing into space and racing toward the very edges of the solar system. Scientists know that these ejections, called CMEs, are caused by magnetic energy building up on the sun, which suddenly releases. But the details of what causes the build up and triggers the release are not precisely understood.

A journal paper in Nature magazine on Oct. 23, 2014, used data from NASA missions to present an example of how something called a magnetic flux rope builds up over time until it is so unstable that even the slightest perturbation will send it flying. Understanding what triggers CMEs is crucial not only for better understanding of our sun, but also to lay the groundwork for predicting when such giant explosions might happen.

"We looked at a well-studied CME from 2006," said Tahar Amari first author on the Nature paper at Ecole Polytechnique in France. "We knew that there had been a great deal of data available for this CME and much analysis already done, but no one had created a comprehensive picture of what happened."

Amari and his colleagues used a traditional meteorology technique to examine the event: Gather observations from the days before the CME to track how the event grew over time. They used observations from the European Space Agency and NASA's Solar and Heliospheric Observatory, or SOHO, and the Japanese Aerospace Exploration Agency and NASA's Hinode, as well as from the Paris-Meudon Observatory.

Scientists created this model to examine the magnetic field before a giant solar eruption – a coronal mass ejection – which occurred on Dec. 13, 2006. The orange lines show magnetic field lines. The grey line represents what's called a flux rope, which built up the day before the event. Image Credit: Amari/Ecole Poytechnique

The team wanted to see if they could distinguish between two broad theories about how the magnetic energy develops. The first model describes a situation in which a series of loops of magnetic fields on the sun – known as an arcade – is the start of every active region CME. 

This arcade has a weak point at the top, a place where the energy from below can burst through once it's great enough. During the eruption a flux rope forms, which can be seen inside the CME as it surges away from the sun.

The second model assumes that the flux rope is there before the CME erupts. In this theory, no weak point is required. Instead, the flux rope gains more and more energy, and becomes increasingly unstable until a disturbance on the sun causes it to release the energy out into space.

Amari and his team used magnetic data from the surface obtained by Hinode, but they also needed magnetic data for the sun's atmosphere, the corona, which is strongly affected by its magnetic field.

"The corona is so hot that most of the techniques to measure the magnetic field don't work," said Amari. "So we developed an efficient and accurate model to compute the magnetic field there, based on the data we had from the surface, and the equations governing the physics of the low corona above active regions."

With these two data sets in hand, the team examined what happened in the four days before the 2006 CME erupted. They could see the magnetic energy building; it was clear something was emerging. Only, however, on the last day did a flux rope develop and only then did it have enough energy built up to power a CME eruption. At this point, some small disruption was enough of a nudge to make the flux rope erupt.

A model of the eruption of a giant magnetic rope that led to a coronal mass ejection on the sun in December 2006.

A model of the eruption of a giant magnetic rope that led to a coronal mass ejection on the sun in December 2006. The model showed that magnetic fields built up for several days before the eruption.

"In this case no weak point up in the atmosphere was needed to allow the energy to be released," said Amari. "There is, instead, a kind of critical value of energy, a value we can compute based on seeing an active magnetic region on the sun. Beneath that value the magnetic field will stay quiet. Above that, it is likely to erupt. There is also a critical height for rising flux rope, beyond which the magnetic loops above can no longer keep it confined."

The team explored the initial conditions from this event and put the information into another dynamical model the team had developed. The simulation mirrored what was actually seen, with an eruption occurring only when the critical energy and height were reached on the last day.

Amari points out that just because this CME contained a flux rope prior to eruption, it doesn't mean that other CMEs can’t erupt based on other physical catalysts. But it clearly describes one mechanism that is at work on the sun.

By measuring and calculating the magnetic fields on the sun, coupled with determining how to measure the critical tipping point where a CME can erupt, the paper offers new ways to determine the possibility of eruption from any given active area on the sun.

Source: Nasa

'Iron Sun' is not a rock band, but a key to how stars transmit energy

Physicist Jim Bailey of Sandia National Laboratories observes a wire array that will heat foam to roughly 4 million degrees until it emits a burst of X-rays that heats a foil target to the interior conditions of the sun. Credit: Photo by Randy Montoya, Sandia National Laboratories

Working at temperatures matching the interior of the sun, researchers at Sandia National Laboratories' Z machine have been able to determine experimentally, for the first time in history, iron's role in inhibiting energy transmission from the center of the sun to near the edge of its radiative band -- the section of the solar interior between the sun's core and outer convection zone.

Because that role is much greater than formerly surmised, the new, experimentally derived amount of iron's opacity -- essentially, its capacity for hindering the transport of radiative energy originating in nuclear fusion reactions deep in the sun's interior -- helps close a theoretical gap in the Standard Solar Model, widely used by astrophysicists as a foundation to model the behavior of stars.

"Our data, when inserted into the theoretical model, bring its predictions more closely into alignment with physical observations," said Sandia lead investigator Jim Bailey. His team's work appeared Jan. 1 in the journal Nature.

The gap between the model and observations appeared in 2000 when analysis of spectra emerging from the sun forced scientists to lower their estimates of energy-absorbing elements such as oxygen, nitrogen and carbon by 30 to 50 percent.

The decreased abundances meant that the model then predicted that energy would arrive at the sun's radiative edge more readily than before. This created a discrepancy between the star's theoretical structure and its measured structure, which is based on variations in temperatures and densities at different locations.

To make the model once again agree with observations, scientists needed a way to balance the decreased resistance to radiation transport caused by the lowered amounts of the elements.

Bailey's experimental group, including Taisuke Nagayama, Guillaume Loisel and Greg Rochau, in painstaking experiments spanning a 10-year period, discovered that the widely used astrophysical estimate of the wavelength-dependent opacity of iron should be increased between 30 to 400 percent. That difference does not represent a large uncertainty but rather how much iron's opacity varies with the wavelength of the radiation.

"This represents roughly half the change in the mean opacity needed to resolve the solar problem, even though iron is only one of many elements that contribute," the authors write in their paper.

Getting accurate data has been difficult, as "the inside of a star is one of the most mysterious places in the universe," Bailey said. "It's too opaque for distant instruments to see inside and analyze reactions within it, and too hot to send a probe into it. It has also been too difficult to run tests under appropriate conditions in a laboratory. So the physics that describes how atoms, embedded in solar plasma, absorb radiation, has never been experimentally tested. Yet that process dominates the way energy generated by nuclear reactions in the sun's interior is transported to the outside.

"Fortunately, in our Z experiments, we can create temperature and density conditions nearly the same as the region inside the sun that affects the discrepancy the most -- the edge of the zone where radiative energy transport dominates -- in a sample that's big enough, lasts long enough, and is uniform enough to test. We used that new capability to measure the opacity of iron, one of a few elements that plays the most important part in radiative energy transfer."

Iron is important because, of all the elements abundant in the sun, it maintains the highest number of bound electrons essential in radiative energy transfer, and thus has a large effect on the outcome of solar models.

Still, the upward revision of opacities as a solution is bound to be controversial.

"No matter what we do, we can't make measurements at all the different conditions we need to know," said Nagayama. "There are 20 elements present, and a large range of temperatures and densities. We study iron because its complex electronic structure is a challenge to represent in opacity theories. And it is important in solar physics. The sun is a test bed to model other stars. Without experimental tests, we don't know if these models are accurate. To the extent we fail to understand the sun, then the workings of other stars are subject to some uncertainty."

Sandia's Z machine creates the temperature of the sun's interior -- about 2.1 million degrees -- in a target about the size of a grain of sand. From that small sample, Bailey could do what theorists cannot: hold in his hand tangible evidence for the way iron atoms behave inside stars.

The target design for recent experiments involved intermingled iron and magnesium, tamped by plastic and beryllium layers on both sides. Radiation streaming through the sample heats up the iron and magnesium, which expand. The plastic restrains the expansion to keep it more uniform for opacity measurements. Magnesium provides information about corresponding density and temperature.

The work was sponsored by the National Nuclear Security Administration and the DOE Office of Science.

Source: DOE/Sandia National Laboratories

Defects in solar cells made of silicon identified

Sergio Castellanos wants continue researching, work in an industry and does not rule out to eventually move to another country. Credit: Image courtesy of Investigación y Desarrollo

Since he was a teenager, engineer Sergio Castellanos had the desire to study abroad to prepare and do research in the best laboratories, particularly on solar energy. With six years of stay in the United States, first at the University of Arizona and now at the Massachusetts Institute of Technology (MIT) in Boston, his dream has come true:

"Working on defects found on silicon and their impact on the efficiency of solar cells made with this material."

This research is carried out to obtain his doctorate from MIT.

"Dislocation is a defect that occurs at high temperatures, of 500 ° C onwards. In my research I analyze these defects and their impact on the efficiency of solar cells made from silicon, since this material is used in over 90 percent of solar panels worldwide ."

The Mexican researcher in Boston explains that the harmful part of the dislocation is interacting with other defects such as metallic impurities within the material of solar cells; they tend to reduce efficiency by -for example- interacting with electrons.

"When having a dislocation is very easy for impurities to settle into a defect in the material. Therefore, in my research I analyze at an early scale what kind of dislocations will be more harmful to the cells, meaning, which ones will interact more with impurities because not all do likewise, hence not all dislocations are equally harmful."

The proposal of Sergio Castellanos at the MIT is to apply a method in wafers of polycrystalline silicon before being processed into solar cells. This method involves using a chemical treatment in order to view the dislocations and analyze the geometric variation on the surface. After making crystallographic analysis as well as X-rays for determining the distribution and concentration of metal impurities, a correlation is made with the geometric appearance of the surface and then, just by looking at the surface, one can deduce what the electrical behavior within material will be.

"The goal is to identify which areas of the material will be more likely for electrons to recombine before being extracted by contacts, becoming less efficient cells."

A little bit of history

When the native of Hermosillo, Sonora (northern state of Mexico), was in high school, he applied for the Massachusetts Institute of Technology (MIT) and was not admitted. He told himself he would not be discouraged because surely the opportunity would could come later. He decided to study mechanical engineering at the Technological Institute of Hermosillo and two years in his parents supported him to finish his degree abroad.

He was transferred to the University of Arizona where he finished his degree. At the university, he became involved in several projects on the subject of energy, as was the case with hydrogen cells, a solar car and installing solar panels.

The Mexican says he enjoyed doing research and started looking for projects and teachers who worked in that area. He spotted four scientists, but wanted to go to MIT because "for any engineer to be in this school is a dream. I had practice in energy research during my bachelor's and for my doctorate I looked for subjects in this area. I applied at several universities and at last I was admitted at MIT in Boston."

His research in solar cells is in the last stage, and once completed in the next year he will make it available to other researchers. This work was presented at various conferences and has received good reviews in terms of utility.

To "finish the tale" on solar cells, the Mexican will complete his studies in six to eight months, and is more than satisfied with the subject that has developed during his research.

Sergio Castellanos wants continue researching, work in an industry and does not rule out to eventually move to another country. In the remaining months he will define his next step. (Agencia ID)

Source: Investigación y Desarrollo

Glimpsing pathway of sunlight to electricity

Andrew H. Marcus and Mark C. Lonergan stand by UO spectroscopy equipment. Credit: Image courtesy of University of Oregon

Four pulses of laser light on nanoparticle photocells in a University of Oregon spectroscopy experiment has opened a window on how captured sunlight can be converted into electricity.

The work, which potentially could inspire devices with improved efficiency in solar energy conversion, was performed on photocells that used lead-sulfide quantum dots as photoactive semiconductor material. The research is detailed in a paper placed online by the journal Nature Communications.

In the process studied, each single photon, or particle of sunlight, that is absorbed potentially creates multiple packets of energy called excitons. These packets can subsequently generate multiple free electrons that generate electricity in a process known as multiple exciton generation (MEG). In most solar cells, each absorbed photon creates just one potential free electron.

Multiple exciton generation is of interests because it can lead to solar cells that generate more electrical current and make them more efficient. The UO work shines new light on the little understood process of MEG in nanomaterials.

While the potential importance of MEG in solar energy conversion is under debate by scientists, the UO spectroscopy experiment -- adapted in a collaboration with scientists at Sweden's Lund University -- should be useful for studying many other processes in photovoltaic nanomaterials, said Andrew H. Marcus, professor of physical chemistry and head of the UO Department of Chemistry and Biochemistry.

Spectroscopic experiments previously designed by Marcus to perform two-dimensional fluorescence spectroscopy of biological molecules were adapted to also measure photocurrent. "Spectroscopy is all about light and molecules and what they do together," Marcus said. "It is a really great probe that helps to tell us about the reaction pathway that connects the beginning of a chemical or physical process to its end.

"The approach is similar to looking at how molecules come together in DNA, but instead we looked at interactions within semiconductor materials," said Marcus, an affiliate in UO's Institute of Molecular Biology, Materials Science Institute and Oregon Center for Optics. "Our method made it possible to look at electronic pathways involved in creating multiple excitons. The existence of this phenomenon had only been inferred through indirect evidence. We believe we have seen the initial steps that lead to MEG-mediated photo conductivity."

The controlled sequencing of laser pulses allowed the seven-member research team to see -- in femtoseconds (a femtosecond is one millionth of one billionth of a second) -- the arrival of light, its interaction with resting electrons and the subsequent conversion into multiple excitons. The combined use of photocurrent and fluorescence two-dimensional spectroscopy, Marcus said, provided complementary information about the reaction pathway.

UO co-author Mark C. Lonergan, professor of physical and materials chemistry, who studies electrical and electrochemical phenomena in solid-state systems, likened the processes being observed to people moving through a corn maze that has one entrance and three exits.
People entering the maze are photons. Those who exit quickly represent absorbed photons that generate unusable heat. People leaving the second exit represent other absorbed photons that generate fluorescence but not usable free electrons. People leaving the final exit signify usable electrical current.

"The question we are interested in is exactly what does the maze look like," Lonergan said. "The problem is we don't have good techniques to look inside the maze to discover the possible pathways through it. The techniques that Andy has developed basically allow us to see into the maze by encoding what is coming out of the system in terms of exactly what is going in. We can visualize what is going on, whether two people coming into the maze shook hands at some point and details about the pathway that led them to come out the electricity exit."

The project began when Tonu Pullerits, who studies ultrafast photochemistry in semiconductor molecular materials at Lund University, approached Marcus about adopting his spectroscopic system to look at solar materials. Khadga J. Karki, a postdoctoral researcher in Pullerits' lab, then visited the UO and teamed with the Marcus and Lonergan groups to reconfigure the equipment.

UO doctoral student Julia R. Widom was a co-leading author on the paper. Other co-authors with Pullerits, Marcus and Lonergan were Joachim Seibt of Lund University and UO graduate student Ian Moody.

Source:  University of Oregon

Scientists get to the heart of fool's gold as a solar material

This crystal of iron pyrite shows the characteristic cubic crystals of 'fool's gold.' A new study led by Song Jin at the University of Wisconsin-Madison identifies defects in pyrite's crystal structure as a critical obstacle to building commercial solar cells from the cheap and abundant iron pyrite material. Credit: University of Wisconsin-Madison Geology Museum

As the installation of photovoltaic solar cells continues to accelerate, scientists are looking for inexpensive materials beyond the traditional silicon that can efficiently convert sunlight into electricity.

Theoretically, iron pyrite -- a cheap compound that makes a common mineral known as fool's gold -- could do the job, but when it works at all, the conversion efficiency remains frustratingly low. Now, a University of Wisconsin-Madison research team explains why that is, in a discovery that suggests how improvements in this promising material could lead to inexpensive yet efficient solar cells.

"We think we now understand why pyrite hasn't worked," says chemistry Professor Song Jin, "and that provides the hope, based on our understanding, for figuring out how to make it work. This could be even more difficult, but exciting and rewarding."

Although most commercial photovoltaic cells nowadays are based on silicon, the light-collecting film must be relatively thick and pure, which makes the production process costly and energy-intensive, says Jin.

A film of iron pyrite -- a compound built of iron and sulfur atoms -- could be 1,000 times thinner than silicon and still efficiently absorb sunlight.

Like silicon, iron and sulfur are common elements in Earth's crust, so solar cells made of iron pyrite could have a significant material cost advantage in large scale deployment. In fact, previous research that balanced factors like theoretical efficiency, materials availability, and extraction cost put iron pyrite at the top of the list of candidates for low-cost and large-scale photovoltaic materials.

In the current online edition of the Journal of the American Chemical Society, Jin and first author Miguel Cabán-Acevedo, a chemistry Ph.D. student, together with other scientists at UW-Madison, explain how they identified defects in the body of the iron pyrite material as the source of inefficiency. The research was supported by the U.S. Department of Energy.
In a photovoltaic material, absorption of sunlight creates oppositely charged carriers, called electrons and holes, that must be separated in order for sunlight to be converted to electricity. The efficiency of a photovoltaic solar cell can be judged by three parameters, Jin says, and the solar cells made of pyrite were almost totally deficient in one: voltage. Without a voltage, a cell cannot produce any power, he points out. Yet based on its essential parameters, iron pyrite should be a reasonably good solar material. "We wanted to know, why is the photovoltage so low," Jin says.

"We did a lot of different measurements and studies to look comprehensively at the problem," says Cabán-Acevedo, "and we think we have fully and definitively shown why pyrite, as a solar material, has not been efficient."

In exploring why pyrite was practically unable to make photovoltaic electricity, many researchers have looked at the surface of the crystals, but Cabán-Acevedo and Jin also looked inside. "If you think of this as a body, many have focused on the skin, but we also looked at the heart," says Cabán-Acevedo, "and we think the major problems lie inside, although there are also problems on the skin."

The internal problems, called "bulk defects," occur when a sulfur atom is missing from its expected place in the crystal structure. These defects are intrinsic to the material properties of iron pyrite and are present even in ultra-pure crystals. Their presence in large numbers eventually leads to the lack of photovoltage for solar cells based on iron pyrite crystals.
Science advances by comprehending causes, Jin says. "Our message is that now we understand why pyrite does not work. If you don't understand something, you must try to solve it by trial and error. Once you understand it, you can use rational design to overcome the obstacle. You don't have to stumble around in the dark."

Source: University of Wisconsin-Madison

A New technique could harvest more of the sun's energy

An ultra-sensitive needle measures the voltage that is generated while the nanospheres are illuminated.
Credit: AMOLF/Tremani - Figure: Artist impression of the plasmo-electric effect.

As solar panels become less expensive and capable of generating more power, solar energy is becoming a more commercially viable alternative source of electricity. However, the photovoltaic cells now used to turn sunlight into electricity can only absorb and use a small fraction of that light, and that means a significant amount of solar energy goes untapped.

A new technology created by researchers from Caltech, and described in a paper published online in the October 30 issue of Science Express, represents a first step toward harnessing that lost energy.

Sunlight is composed of many wavelengths of light. In a traditional solar panel, silicon atoms are struck by sunlight and the atoms' outermost electrons absorb energy from some of these wavelengths of sunlight, causing the electrons to get excited. Once the excited electrons absorb enough energy to jump free from the silicon atoms, they can flow independently through the material to produce electricity. This is called the photovoltaic effect -- a phenomenon that takes place in a solar panel's photovoltaic cells.

Although silicon-based photovoltaic cells can absorb light wavelengths that fall in the visible spectrum -- light that is visible to the human eye -- longer wavelengths such as infrared light pass through the silicon. These wavelengths of light pass right through the silicon and never get converted to electricity -- and in the case of infrared, they are normally lost as unwanted heat.

"The silicon absorbs only a certain fraction of the spectrum, and it's transparent to the rest. If I put a photovoltaic module on my roof, the silicon absorbs that portion of the spectrum, and some of that light gets converted into power. But the rest of it ends up just heating up my roof," says Harry A. Atwater, the Howard Hughes Professor of Applied Physics and Materials Science; director, Resnick Sustainability Institute, who led the study.
Now, Atwater and his colleagues have found a way to absorb and make use of these infrared waves with a structure composed not of silicon, but entirely of metal.

The new technique they've developed is based on a phenomenon observed in metallic structures known as plasmon resonance. Plasmons are coordinated waves, or ripples, of electrons that exist on the surfaces of metals at the point where the metal meets the air.
While the plasmon resonances of metals are predetermined in nature, Atwater and his colleagues found that those resonances are capable of being tuned to other wavelengths when the metals are made into tiny nanostructures in the lab.

"Normally in a metal like silver or copper or gold, the density of electrons in that metal is fixed; it's just a property of the material," Atwater says. "But in the lab, I can add electrons to the atoms of metal nanostructures and charge them up. And when I do that, the resonance frequency will change."

"We've demonstrated that these resonantly excited metal surfaces can produce a potential" -- an effect very similar to rubbing a glass rod with a piece of fur: you deposit electrons on the glass rod. "You charge it up, or build up an electrostatic charge that can be discharged as a mild shock," he says. "So similarly, exciting these metal nanostructures near their resonance charges up those metal structures, producing an electrostatic potential that you can measure."

This electrostatic potential is a first step in the creation of electricity, Atwater says. "If we can develop a way to produce a steady-state current, this could potentially be a power source. He envisions a solar cell using the plasmoelectric effect someday being used in tandem with photovoltaic cells to harness both visible and infrared light for the creation of electricity.

Although such solar cells are still on the horizon, the new technique could even now be incorporated into new types of sensors that detect light based on the electrostatic potential.
"Like all such inventions or discoveries, the path of this technology is unpredictable," Atwater says. "But any time you can demonstrate a new effect to create a sensor for light, that finding has almost always yielded some kind of new product."


This work was published in a paper titled, "Plasmoelectric Potentials in Metal Nanostructures." Other coauthors include first author Matthew T. Sheldon, a former postdoctoral scholar at Caltech; Ana M. Brown, an applied physics graduate student at Caltech; and Jorik van de Groep and Albert Polman from the FOM Institute AMOLF in Amsterdam. The study was funded by the Department of Energy, the Netherlands Organization for Scientific Research, and an NSF Graduate Research Fellowship.

Source: California Institute of Technology

The Matched 'hybrid' systems may hold key to wider use of renewable energy

Wind farms such as this one in Idaho might be combined with other forms of alternative energy to better balance the output of sustainable energy. Credit: Nordex USA/US Department of Energy

The use of renewable energy in the United States could take a significant leap forward with improved storage technologies or more efforts to "match" different forms of alternative energy systems that provide an overall more steady flow of electricity, researchers say in a new report.

Historically, a major drawback to the use and cost-effectiveness of alternative energy systems has been that they are too variable -- if the wind doesn't blow or the sun doesn't shine, a completely different energy system has to be available to pick up the slack. This lack of dependability is costly and inefficient.

But in an analysis just published in The Electricity Journal, scientists say that much of this problem could be addressed with enhanced energy storage technology or by developing "hybrid" systems in which, on a broader geographic scale, one form of renewable energy is ramping up even while the other is declining.

"Wind energy is already pretty cost-competitive and solar energy is quickly getting there," said Anna Kelly, a graduate student in the School of Public Policy at Oregon State University, and an energy policy analyst. "The key to greater use of these and other technologies is to match them in smart-grid, connected systems.

"This is already being done successfully in a number of countries and the approach could be expanded."

For instance, the wind often blows more strongly at night in some regions, Kelly said, and solar technology can only produce energy during the day. By making more sophisticated use of that basic concept in a connected grid, and pairing it with more advanced forms of energy storage, the door could be opened for a much wider use of renewable energy systems, scientists say.

"This is more than just an idea, it's a working reality in energy facilities around the world, in places like Spain, Morocco and China, as well as the U.S.," Kelly said. "Geothermal is being paired with solar; wind and solar with lithium-ion batteries; and wind and biodiesel with batteries. By helping to address the price issue, renewable energy is being produced in hybrid systems by real, private companies that are making real money."

Advanced energy storage could be another huge key to making renewable energy more functional, and one example is just being developed in several cooperating states in the West. Electricity is being produced by efficient wind farms in Wyoming; transmitted to Utah where it's being stored via compressed air in certain rock formations; and ultimately used to help power Los Angeles.

This $8 billion system could be an indicator of things to come, since compressed air can rapidly respond to energy needs and be readily scaled up to be cost-competitive at a significant commercial level.

"There are still a number of obstacles to overcome," said Joshua Merritt, a co-author on the report and also a graduate student in mechanical engineering and public policy at OSU. "Our transmission grids need major improvements so we can more easily produce energy and then send it to where it's needed. There are some regulatory hurdles to overcome. And the public has to more readily accept energy systems like wind, wave or solar in practice, not just in theory."

The "not in my back yard" opposition to renewable energy systems is still a reality, the researchers said, and there are still some environmental concerns about virtually any form of energy, whether it's birds killed by wind turbine rotors, fish losses in hydroelectric dams or chemical contaminants from use of solar energy.

The near future may offer more options, the researchers said. Advanced battery storage technologies are becoming more feasible. Wave or tidal energy may become a real contributor, and some of those forces are more predictable and stable by definition. And the birth of small, modular nuclear reactors -- which can be built at lower cost and produce no greenhouse gas emissions -- could play a significant role in helping to balance energy outflows from renewable sources.

The long-term goal, the report concluded, is to identify technologies that can work in a hybrid system that offers consistency, dependability and doesn't rely on fossil fuels. With careful matching of systems, improved transmission abilities and some new technological advances, that goal may be closer than realized, they said.

"With development, the cost of these hybrid systems will decrease and become increasingly competitive, hopefully playing a larger role in power generation in the future," the researchers wrote in their conclusion.

Source: Oregon State University

Offsetting global warming: Targeting solar geoengineering to minimize risk and inequality

Sunset in the Arctic. A new study at Harvard explores the feasibility of using cautious and targeted solar geoengineering to counter the loss of Arctic sea ice.

A new study suggests that solar geoengineering can be tailored to reduce inequality or to manage specific risks like the loss of Arctic sea ice. By tailoring geoengineering efforts by region and by need, a new model promises to maximize the effectiveness of solar radiation management while mitigating its potential side effects and risks.

Developed by a team of leading researchers, the study was published in the November issue of Nature Climate Change.

Solar geoengineering, the goal of which is to offset the global warming caused by greenhouse gases, involves reflecting sunlight back into space. By increasing the concentrations of aerosols in the stratosphere or by creating low-altitude marine clouds, the as-yet hypothetical solar geoengineering projects would scatter incoming solar heat away from Earth's surface.

Critics of geoengineering have long warned that such a global intervention would have unequal effects around the world and could result in unforeseen consequences. They argue that the potential gains may not be worth the risk.

Gordon McKay Professor of Applied Physics at the Harvard School of Engineering and Applied Sciences (SEAS) and Professor of Public Policy at Harvard Kennedy School. "Instead, we can be thoughtful about various tradeoffs to achieve more selective results, such as the trade-off between minimizing global climate changes and minimizing residual changes at the worst-off location."
The study -- developed in collaboration with Douglas G. MacMartin of the California Institute of Technology, Ken Caldeira of the Carnegie Institution for Science, and Ben Kravitz, formerly of Carnegie and now at the Department of Energy -- explores the feasibility of using solar geoengineering to counter the loss of Arctic sea ice.

"There has been a lot of loose talk about region-specific climate modification. By contrast, our research uses a more systematic approach to understand how geoengineering might be used to limit a specific impact. We found that tailored solar geoengineering might limit Arctic sea ice loss with several times less total solar shading than would be needed in a uniform case."

Generally speaking, greenhouse gases tend to suppress precipitation, and an offsetting reduction in the amount of sunlight absorbed by Earth would not restore this precipitation. Both greenhouse gases and aerosols affect the distribution of heat and rain on this planet, but they change the temperature and precipitation in different ways in different places. The researchers suggest that varying the amount of sunlight deflected away from Earth both regionally and seasonally could combat some of this problem.

"These results indicate that varying geoengineering efforts by region and over different periods of time could potentially improve the effectiveness of solar geoengineering and reduce climate impacts in at-risk areas," says co-author Ken Caldeira, Senior Scientist in the Department of Global Ecology at the Carnegie Institution for Science.

The researchers note that while their study used a state-of-the-art model, any real-world estimates of the possible impact of solar radiation management would need to take into account various uncertainties. Further, any interference in Earth's climate system, whether intentional or unintentional, is likely to produce unanticipated outcomes.

"While more work needs to be done, we have a strong model that indicates that solar geoengineering might be used in a far more nuanced manner than the uniform one-size-fits-all implementation that is often assumed. One might say that one need not think of it as a single global thermostat. This gives us hope that if we ever do need to implement engineered solutions to combat global warming, that we would do so with a bit more confidence and a great ability to test it and control it."


Source: Harvard University